Vladimir Mikhailovich Fokin

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Produções bibliográficas

• RODRIGUES, LORENA R. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; Schmelzer, Jürn W.P. ; Zanotto, Edgar D. . Relaxation effect on crystal nucleation in a glass unveiled by experimental, numerical, and analytical approaches. ACTA MATERIALIA , v. 223, p. 117458, 2022.

• FOKIN, VLADIMIR.M. ; ABYZOV, ALEXANDER.S. ; YURITSYN, NIKOLAY.S. ; SCHMELZER, JÜRN.W.P. ; ZANOTTO, EDGAR.D. . Effect of structural relaxation on crystal nucleation in glasses. ACTA MATERIALIA , v. 203, p. 116472, 2021.

• RODRIGUES, LORENA R. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; ZANOTTO, EDGAR DUTRA . Effect of structural relaxation on crystal nucleation in a soda-lime-silica glass. JOURNAL OF THE AMERICAN CERAMIC SOCIETY , v. 104, p. 3212-3223, 2021.

• SCHMELZER, JÜRN W. P. ; TROPIN, TIMUR V. ; FOKIN, VLADIMIR M. ; Abyzov, Alexander S. ; Zanotto, Edgar D. . Effects of Glass Transition and Structural Relaxation on Crystal Nucleation: Theoretical Description and Model Analysis. Entropy , v. 22, p. 1098, 2020.

• MACENA, GUILHERME S. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; Zanotto, Edgar D. ; FERREIRA, EDUARDO B. . Off-stoichiometry effects on crystal nucleation and growth kinetics in soda-lime-silicate glasses. The combeite (Na2O-2CaO-3SiO2) - devitrite (Na2O-3CaO-6SiO2) joint. ACTA MATERIALIA , v. 196, p. 191-199, 2020.

• Abyzov, Alexander S. ; SCHMELZER, JÜRN W. P. ; FOKIN, VLADIMIR M. ; Zanotto, Edgar D. . Crystallization of Supercooled Liquids: Self-Consistency Correction of the Steady-State Nucleation Rate. Entropy , v. 22, p. 558, 2020.

• SCHMELZER, JÜRN W. P. ; Abyzov, Alexander S. ; FERREIRA, EDUARDO B. ; FOKIN, VLADIMIR M. . Curvature dependence of the surface tension and crystal nucleation in liquids. International Journal of Applied Glass Science , v. 10, p. 57-68, 2019.

• BUCHNER, SILVIO ; KULBIEDA, FELIPE R. ; FOKIN, VLADIMIR M. ; SOARES, PAULO ; MACHADO, ÁLVARO D?. ; SCHMELZER, JÜRN W. P. ; BALZARETTI, NAIRA M. . Thermal stability of lithium metasilicate produced under high pressure from lithium disilicate glass. International Journal of Applied Glass Science , v. 10, p. 522-531, 2019.

• SCHMELZER, JÜRN W. P. ; TROPIN, TIMUR V. ; FOKIN, VLADIMIR M. ; ZHANG, RUI ; ABDELAZIZ, AMIR ; CHUA, YEONG ZEN ; MADHAVI, VADLAMUDI ; SHAFFER, TIM D. ; SCHICK, CHRISTOPH . Correlation between glass transition temperature and the width of the glass transition interval. International Journal of Applied Glass Science , v. 10, p. 502-513, 2019.

• FOKIN, VLADIMIR M. ; Abyzov, Alexander S. ; RODRIGUES, ALISSON M. ; POMPERMAYER, ROGERIO Z. ; DE SILVA MACENA, GUILHERME ; Zanotto, Edgar D. ; FERREIRA, EDUARDO B. . Effect of non-stoichiometry on the crystal nucleation and growth in oxide glasses. ACTA MATERIALIA , v. 180, p. 317-328, 2019.

• NUERNBERG, R.B. ; BELLO, T.S. ; FOKIN, V.M. ; ZANOTTO, E.D. ; RODRIGUES, A.C.M. . Non-stoichiometric crystallization of Li2SiO3-CaSiO3 glasses: Residual glass composition from ionic conductivity. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 510, p. 158-165, 2019.

• RODRIGUES, ALISSON M. ; CASSAR, DANIEL R. ; FOKIN, VLADIMIR M. ; ZANOTTO, EDGAR DUTRA . Crystal growth and viscous flow in barium disilicate glass. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 479, p. 55-61, 2018.

• YURITSYN, NIKOLAY S. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. . Distinct crystal growth on the surface and in the interior of Na2O2CaO3SiO2 glass. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 498, p. 42-48, 2018.

• Schmelzer, Jürn W.P. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; SCHICK, CHRISTOPH . Kauzmann paradox and the crystallization of glass-forming melts. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 501, p. 21-35, 2018.

• Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; Zanotto, Edgar D. . Predicting homogeneous nucleation rates in silicate glass-formers. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 500, p. 231-234, 2018.

• SANTOS, GISELE G. ; SERBENA, FRANCISCO C. ; FOKIN, VLADIMIR M. ; Zanotto, Edgar D. . Microstructure and mechanical properties of nucleant-free Li 2 O-CaO-SiO 2 glass-ceramics. ACTA MATERIALIA , v. 130, p. 347-360, 2017.

• Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; YURITSYN, NIKOLAY S. ; RODRIGUES, ALISSON MENDES ; Schmelzer, Jürn W.P. . The effect of heterogeneous structure of glass-forming liquids on crystal nucleation. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 462, p. 32-40, 2017.

• SCHMELZER, JÜRN W. P. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. . Thermodynamic Aspects of Pressure-Induced Crystallization: Kauzmann Pressure. International Journal of Applied Glass Science , v. 7, p. 474-485, 2016.

• FOKIN, VLADIMIR M. ; Abyzov, Alexander S. ; Zanotto, Edgar D. ; CASSAR, DANIEL R. ; RODRIGUES, ALISSON M. ; Schmelzer, Jürn W.P. . Crystal nucleation in glass-forming liquids: Variation of the size of the -structural units- with temperature. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 447, p. 35-44, 2016.

• Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; RODRIGUES, ALISSON MENDES ; Zanotto, Edgar D. ; Schmelzer, Jürn W.P. . The effect of elastic stresses on the thermodynamic barrier for crystal nucleation. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 432, p. 325-333, 2016.

• REIS, RAPHAEL M. C. V. ; FOKIN, VLADIMIR M. ; Zanotto, Edgar D. . Determination of Crystal Growth Rates in Glasses Over a Temperature Range Using a Single DSC Run. JOURNAL OF THE AMERICAN CERAMIC SOCIETY , v. 99, p. n/a-n/a, 2016.

• SCHMELZER, JÜRN W. P. ; FOKIN, VLADIMIR M. ; Abyzov, Alexander S. . Crystallization of Glass: What We Know, What We Need to Know. International Journal of Applied Glass Science , v. 7, p. 253-261, 2016.

• GALLO, LEONARDO SANT'ANA ; DE MARCHI MOSCA, TIAGO ; TEIDER, BRUNO HENRIQUE ; POLYAKOVA, IRINA ; RODRIGUES, ANA CANDIDA MARTINS ; ZANOTTO, EDGAR DUTRA ; FOKIN, VLADIMIR M. . Effects of lithium oxide on the crystallization kinetics of Na2O2CaO3SiO2 glass. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 408, p. 102-114, 2015.

• Schmelzer, Jürn W.P. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; SCHICK, CHRISTOPH ; Zanotto, Edgar D. . Crystallization of glass-forming liquids: Maxima of nucleation, growth, and overall crystallization rates. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 429, p. 24-32, 2015.

• Schmelzer, Jürn W.P. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; SCHICK, CHRISTOPH ; Zanotto, Edgar D. . Crystallization in glass-forming liquids: Effects of decoupling of diffusion and viscosity on crystal growth. JOURNAL OF NON-CRYSTALLINE SOLIDS , v. 429, p. 45-53, 2015.

• ZHURAVLEV, EVGENY ; SCHMELZER, JÜRN W. P. ; Abyzov, Alexander S. ; FOKIN, VLADIMIR M. ; ANDROSCH, RENÉ ; SCHICK, CHRISTOPH . Experimental Test of Tammann?s Nuclei Development Approach in Crystallization of Macromolecules. CRYSTAL GROWTH & DESIGN , v. 15, p. 786-798, 2015.

• FOKIN, VLADIMIR M. ; Reis, Raphael M.C.V. ; Abyzov, Alexander S. ; CHINAGLIA, CLEVER R. ; Schmelzer, Jürn W.P. ; Zanotto, Edgar D. . Non-stoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 2 - Effect of the residual liquid. Journal of Non-Crystalline Solids , v. 379, p. 131-144, 2013.

• DYAMANT, I. ; ABYZOV, A.S. ; FOKIN, V.M. ; ZANOTTO, E.D. ; LUMEAU, J. ; GLEBOVA, L.N. ; GLEBOV, L.B. . Crystal nucleation and growth kinetics of NaF in photo-thermo-refractive glass. Journal of Non-Crystalline Solids , v. 378, p. 115-120, 2013.

• FOKIN, VLADIMIR M. ; Reis, Raphael M.C.V. ; Abyzov, Alexander S. ; CHINAGLIA, CLEVER R. ; Zanotto, Edgar D. . Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 1 - Crystal nucleation and growth rates. Journal of Non-Crystalline Solids , v. 362, p. 56-64, 2013.

• YAKOVIS, EL ; ARTEMIEVA, AV ; FOKIN, MV ; VARFOLOMEEVA, MA . Intraspecific variation in stable isotope signatures indicates no small-scale feeding interference between a horse mussel and an ascidian. Marine Ecology. Progress Series (Halstenbek) , v. 467, p. 113-120, 2012.

• Souza, Guilherme P. ; Fokin, Vladimir M. ; Rodrigues, Camila F. ; Rodrigues, Ana Candida M. ; Zanotto, Edgar D. ; Lumeau, Julien ; Glebova, Larissa ; Glebov, Leonid B. ; FOKIN, V. M. . Liquid-Liquid Phase Separation in Photo-Thermo-Refractive Glass. Journal of the American Ceramic Society , v. 94, p. 145-150, 2011.

• NASCIMENTO, MARCIO LUIS FERREIRA ; FOKIN, VLADIMIR MIHAILOVICH ; ZANOTTO, EDGAR DUTRA ; Abyzov, Alexander S. . Dynamic processes in a silicate liquid from above melting to below the glass transition. The Journal of Chemical Physics , v. 135, p. 194703, 2011.

• SOUZA, G.P. ; FOKIN, V.M. ; BAPTISTA, C.A. ; ZANOTTO, E.D. ; LUMEAU, J. ; GLEBOVA, L. ; GLEBOV, L.B. . Effect of Bromine on NaF Crystallization in Photo-Thermo-Refractive Glass. Journal of the American Ceramic Society , v. 94, p. 2906-2911, 2011.

• Abyzov, Alexander S. ; Schmelzer, Jürn W.P. ; FOKIN, VLADIMIR M. . Theory of pore formation in glass under tensile stress: Generalized Gibbs approach. Journal of Non-Crystalline Solids , v. 357, p. 3474-3479, 2011.

• Fokin, Vladimir M. ; Souza, Guilherme P. ; Zanotto, Edgar D. ; Lumeau, Julien ; Glebova, Larissa ; Glebov, Leonid B. ; FOKIN, V. M. . Sodium Fluoride Solubility and Crystallization in Photo-Thermo-Refractive Glass. Journal of the American Ceramic Society , v. 93, p. 716-721, 2010.

• Fokin, Vladimir M. ; Cabral, Aluísio A. ; Reis, Raphael M.C.V. ; Nascimento, Marcio L.F. ; Zanotto, Edgar D. ; FOKIN, V. M. . Critical assessment of DTADSC methods for the study of nucleation kinetics in glasses. Journal of Non-Crystalline Solids , v. 356, p. 358-367, 2010.

• Fokin, Vladimir M. ; Zanotto, Edgar D. ; Schmelzer, Jürn W.P. ; FOKIN, V. M. . On the thermodynamic driving force for interpretation of nucleation experiments. Journal of Non-Crystalline Solids , v. 356, p. 2185-2191, 2010.

• Abyzov, Alexander S. ; Schmelzer, Jürn W.P. ; Fokin, Vladimir M. ; FOKIN, V. M. . Elastic stresses in crystallization processes in finite domains. Journal of Non-Crystalline Solids , v. 356, p. 1670-1678, 2010.

• Fokin, Vladimir M. ; Abyzov, Alexander S. ; Schmelzer, Jürn W.P. ; Zanotto, Edgar D. ; FOKIN, V. M. . Stress induced pore formation and phase selection in a crystallizing stretched glass. Journal of Non-Crystalline Solids , v. 356, p. 1679-1688, 2010.

• Cabral, Aluisio A. ; Fokin, Vladimir M. ; Zanotto, Edgar D. ; FOKIN, V. M. . On the Determination of Nucleation Rates in Glasses by Nonisothermal Methods. Journal of the American Ceramic Society , v. 93, p. 2438-2440, 2010.

• SCHMELZER, JÜRN W. P. ; FOKIN, VLADIMIR M. ; Abyzov, Alexander S. ; Zanotto, Edgar D. ; GUTZOW, IVAN . How Do Crystals Form and Grow in Glass-Forming Liquids: Ostwald's Rule of Stages and Beyond. International Journal of Applied Glass Science , v. 1, p. 16-26, 2010.

• Souza, Guilherme P. ; FOKIN, V. M. ; Zanotto, Edgar D. ; Lumeau, Julien ; Glebova, Larissa ; Glebov, Leonid B. . Micro and nanostructures in partially crystallised photothermorefractive glass. Physics and Chemistry of Glasses , v. 50, p. 311-320, 2009.

• NAUMOV, A. D. ; KHALAMAN, V. V. ; FOKIN, M. V. . Long-term dynamics of the abundance of several intertidal polychaetes in two inlets of Kandalaksha Bay (White Sea). RUSS J MAR BIOL+ , v. 35, p. 381-387, 2009.

• FOKIN, V. M. ; Yuritsyn, N. S. ; Zanotto, E. D. ; Schmelzer, J. W. P. ; Cabral, A. A. . Nucleation time-lag from nucleation and growth experiments in deeply undercooled glass-forming liquids. Journal of Non-Crystalline Solids , p. 1, 2008.

• BERTHIER, T ; FOKIN, V ; ZANOTTO, E . New large grain, highly crystalline, transparent glassceramics. Journal of Non-Crystalline Solids , v. 354, p. 1721-1730, 2008.

• RODRIGUES, A ; NIITSU, G ; ZANOTTO, E ; PRADO, M ; FOKIN, V . Erratum to Crystallization kinetics of 1Na2O2CaO3SiO2 glass monitored by electrical conductivity measurements [J. Non-Cryst. Solids 353 (2007) 22372243]. Journal of Non-Crystalline Solids , v. 354, p. 3098-3098, 2008.

• FOKIN, V. M. ; Zanotto, E. D. . Continuous compositional changes of crystal and liquid during crystallization of a sodium calcium silicate glass. Journal of Non-Crystalline Solids , v. 353, p. 2459-2468, 2007.

• FOKIN, V. M. ; Schmelzer, J. W. P. ; Nascimento, M. L. F. ; Zanotto, E. D. . Diffusion coefficients for crystal nucleation and growth in deeply undercooled glass-forming liquids. Journal of Chemical Physics , v. 126, p. 234507, 2007.

• da Cunha, T. B. ; Wu, J. P. ; Peitl, O. ; FOKIN, V. M. ; Zanotto, E. D. ; Iannucci, L. ; Boccaccini, A. R. . Mechanical properties and impact resistance of a new transparent glass-ceramic. Advanced Engineering Materials , v. 9, p. 191-196, 2007.

• Guencheva, V. ; Rüssel, C. ; FOKIN, V. M. ; Gutzow, I. . The induced crystallisation of glass forming melts. Part 2. Influence of surfactants and non-surfactant soluble additives. Physics and Chemistry of Glasses , v. 48, p. 48-60, 2007.

• RODRIGUES, A ; NIITSU, G ; ZANOTTO, E ; PRADO, M ; FOKIN, V . Crystallization kinetics of 1Na2O2CaO3SiO2glass monitored by electrical conductivity measurements. Journal of Non-Crystalline Solids , v. 353, p. 2237-2243, 2007.

• FOKIN, V. M. ; Zanotto, E. D. ; Yuritsyn, N. S. ; Schmelzer, J. W. P. . Homogeneous crystal nucleation in silicate glasses: A 40 years perspective. Journal of Non-Crystalline Solids , v. 352, p. 2681-2714, 2006.

• Schmelzer, J. W. P. ; Zanotto, E. D. ; Avramov, I. ; FOKIN, V. M. . Stress development and relaxation during crystal growth in glass-forming liquids. Journal of Non-Crystalline Solids , v. 352, p. 434-443, 2006.

• FOKIN, V. M. ; Zanotto, E. D. ; Schmelzer, J. W. P. ; Potapov, O. V. . New insights on the thermodynamic barrier for nucleation in glasses: The case of lithium disilicate. Journal of Non-Crystalline Solids , v. 351, p. 1491-1499, 2005.

• FOKIN, V. M. ; Nascimento, M. L. F. ; Zanotto, E. D. . Correlation between maximum crystal growth rate and glass transition temperature of silicate glasses. Journal of Non-Crystalline Solids , v. 351, p. 789-794, 2005.

• Schmelzer, J. W. P. ; Zanotto, E. D. ; FOKIN, V. M. . Pressure dependence of viscosity. Journal of Chemical Physics , v. 122, p. 074511, 2005.

• Cabral, A. A. ; FOKIN, V. M. ; Zanotto, E. D. . Nanocrystallization of fresnoite glass. II. Analysis of homogeneous nucleation kinetics. Journal of Non-Crystalline Solids , v. 343, p. 85-90, 2004.

• Schmelzer, J. W. P. ; Gokhman, A. R. ; FOKIN, V. M. . Dynamics of first-order phase transitions in multicomponent systems: a new theoretical approach. Journal of Colloid and Interface Science , v. 272, p. 109-133, 2004.

• Schmelzer, J. W. P. ; Potapov, O. V. ; FOKIN, V. M. ; Müller, R. ; Reinsch, S. . The effect of elastic stress and relaxation on crystal nucleation in lithium disilicate glass. Journal of Non-Crystalline Solids , v. 333, p. 150-160, 2004.

• FOKIN, V. M. ; Yuritsyn, N. S. ; Potapov, O. V. ; Shakhmatkin, B. A. ; Vedishcheva, N. M. ; Ugolkov, V. L. ; Cherepova, A. G. . Nucleation of crystals in lithium-silicate glasses. Russian Journal of Physical Chemistry , v. 77, p. 146-148, 2003.

• Zanotto, E. D. ; FOKIN, V. M. . Recent studies of internal and surface nucleation in silicate glasses. Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences , v. 361, p. 591-612, 2003.

• FOKIN, V. M. ; Potapov, O. V. ; Zanotto, E. D. ; Spiandorello, F. M. ; Ugolkov, V. L. ; Pevzner, B. Z. . Mutant crystals in Na2O-2CaO-3SiO2 glasses. Journal of Non-Crystalline Solids , v. 331, p. 240-253, 2003.

• Soares, P. C. ; FOKIN, V. M. ; Zanotto, E. D. ; Jain, H. . TEM and XRD study of early crystallization of lithium disilicate glasses. Journal of Non-Crystalline Solids , v. 331, p. 217-227, 2003.

• Cabral, A. A. ; FOKIN, V. M. ; Zanotto, E. D. ; Chinaglia, C. R. . Nanocrystallization of fresnoite glass. I. Nucleation and growth kinetics. Journal of Non-Crystalline Solids , v. 330, p. 174-186, 2003.

• FOKIN, V. M. ; Potapov, O. V. ; Ugolkov, V. L. ; Zanotto, E. D. ; Spiandorello, F. M. . The kinetics of crystallization of solid solutions in a glass of the stoichiometric composition Na2O-2CaO-3SiO2. Russian Journal of Physical Chemistry , v. 77, p. 1639-1641, 2003.

• FOKIN, V. M. ; Zanotto, E. D. ; Schmelzer, J. W. P. . Homogeneous nucleation versus glass transition temperature of silicate glasses. Journal of Non-Crystalline Solids , v. 321, p. 52-65, 2003.

• Kukushkin, S. A. ; Grigor'ev, D. A. ; Indeitsev, D. A. ; Potapov, O. V. ; FOKIN, V. M. . Kinetics of the initial stage of crystallization at a spatially inhomogeneous temperature distribution. Glass Physics and Chemistry , v. 27, p. 250-258, 2001.

• FOKIN, V. M. ; Zanotto, E. D. ; Schmelzer, J. W. P. . Method to estimate crystal/liquid surface energy in melt crystallization. Glass Science and Technology (Frankfurt) , v. 73, p. 197-204, 2000.

• FOKIN, V. M. ; Zanotto, E. D. ; Schmelzer, J. W. P. . Method to estimate crystal/liquid surface energy by dissolution of subcritical nuclei. Journal of Non-Crystalline Solids , v. 278, p. 24-34, 2000.

• Müller, R. ; Zanotto, E. D. ; FOKIN, V. M. . Surface crystallization of silicate glasses: nucleation sites and kinetics. Journal of Non-Crystalline Solids , v. 274, p. 208-231, 2000.

• FOKIN, V. M. ; Zanotto, E. D. . Crystal nucleation in silicate glasses: the temperature and size dependence of crystal/liquid surface energy. Journal of Non-Crystalline Solids , v. 265, p. 105-112, 2000.

• Potapov, O. V. ; FOKIN, V. M. ; Ugolkov, V. L. . Influence of Na2O content on the nucleation kinetics in glasses of compositions close to the Na2O-2CaO-3SiO2 stoichiometry. Glass Physics and Chemistry , v. 26, p. 27-32, 2000.

• Potapov, O. V. ; FOKIN, V. M. ; Ugolkov, V. L. ; Filipovich, V. N. . Influence of Na2O content on the nucleation kinetics in the glasses of compositions close to stoichiometry Na2O-2CaO-3SiO2. Glass Physics and Chemistry , v. 26, p. 39-47, 2000.

• FOKIN, V. M. ; Potapov, O. V. ; Chinaglia, C. R. ; Zanotto, E. D. . The effect of pre-existing crystals on the crystallization kinetics of a soda-lime-silica glass. The courtyard phenomenon. Journal of Non-Crystalline Solids , v. 258, p. 180-186, 1999.

• Filipovich, V. N. ; Kalinina, A. M. ; FOKIN, V. M. . Bulk and surface crystallization of silicate glasses. Inorganic Materials , v. 35, p. 842-846, 1999.

• Filipovich, V. N. ; Kalinina, A. M. ; FOKIN, V. M. ; Sycheva, G. A. . Kinetic regularities of bulk and surface crystal nucleation in silicate glasses. Glass Physics and Chemistry , v. 25, p. 246-253, 1999.

• Potapov, O. V. ; FOKIN, V. M. ; Filipovich, V. N. . Nucleation and crystal growth in water containing soda-lime-silica glasses. Journal of Non-Crystalline Solids , v. 247, p. 74-78, 1999.

• FOKIN, V. M. ; Zanotto, E. D. . Surface and volume nucleation and growth in TiO2-cordierite glasses. Journal of Non-Crystalline Solids , v. 246, p. 115-127, 1999.

• Filipovich, V. N. ; FOKIN, V. M. ; Kalinina, A. M. ; Yuritsyn, N. S. . Bulk and surface crystallization of silicate glasses. Inorganic Materials , v. 35, p. 990-995, 1999.

• Potapov, O. V. ; FOKIN, V. M. ; Filipovich, V. N. . Influence of water on the crystal nucleation and growth in the Na2O-2CaO-3SiO2 glass. Glass Physics and Chemistry , v. 24, p. 337-341, 1998.

• Diaz-Mora, N. ; Zanotto, E. D. ; FOKIN, V. M. . Crystal growth and viscous flow in cordierite and other glasses. Physics and Chemistry of Glasses , v. 39, p. 91-97, 1998.

• Cabral, A. A. ; FOKIN, V. M. ; Zanotto, E. D. ; Chinaglia, C. R. . Crystallization kinetics of fresnoite glass. Glass Science and Technology (Frankfurt) , v. 71, p. 131-136, 1998.

• Potapov, O. V. ; FOKIN, V. M. ; Filipovich, V. N. ; Kalinina, A. M. . Water effect on the crystals nucleation and growth in the glass of composition Na2O.2CaO.3SiO2. Glass Physics and Chemistry , v. 24, p. 484-490, 1998.

• FOKIN, V. M. ; Yuritsyn, N. S. ; Filipovich, V. N. ; Kalinina, A. M. . Kinetics of the mu-cordierite crystal nucleation on polished cordierite glass. Journal of Non-Crystalline Solids , v. 219, p. 37-41, 1997.

• FOKIN, V. M. ; Yuritsyn, N. S. . The nucleation and growth rates of sodium metasilicate crystals in sodium silicate glass 44Na2O-56SiO2. Glass Physics and Chemistry , v. 23, p. 236-239, 1997.

• Filipovich, V. N. ; FOKIN, V. M. ; Yuritsyn, N. S. ; Kalinina, A. M. . Crystal nucleation on the glass surface. Theory and Experiment. Thermochimica Acta , v. 280, p. 205-222, 1996.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Crystal nucleation and growth in the surface crystallization of cordierite glass. Glass Physics and Chemistry , v. 20, p. 116-124, 1994.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Surface and crystal nucleation in cordierite glass: kinetics and a theoretical model. Glass Physics and Chemistry , v. 20, p. 125-132, 1994.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Crystal nucleation and growth in the surface crystallization of cordierite glass. Glass Physics And Chemistry , v. 20, p. 171-183, 1994.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Surface crystal nucleation in cordierite glass: kinetics and a theoretical model. Glass Physics And Chemistry , v. 20, p. 184-195, 1994.

• FOKIN, V. M. ; Yuritsyn, N. S. ; Kalinina, A. M. ; Filipovich, V. N. . The temperature dependence of the mu-cordierite crystal nucleation rate on the polished surface of cordierite glass. Glass Science and Technology (Frankfurt) , v. 67c, p. 392-395, 1994.

• Filipovich, V. N. ; Zhukovskaya, T. A. ; Kalinina, A. M. ; FOKIN, V. M. . Effect of fronzen pre-critical and post-critical nuclei on the formation of crystals in glasses. Glass Physics and Chemistry , v. 15, p. 375-379, 1990.

• Filipovich, V. N. ; Kalinina, A. M. ; FOKIN, V. M. . Effect of frozen subcritical nuclei on crystal nucleation in glasses. Glass Physics and Chemistry , v. 15, p. 643-647, 1989.

• Kalinina, A. M. ; Sycheva, G. A. ; Filipovich, V. N. ; FOKIN, V. M. . Autocatalyzed nucleation of lithium disilicate in the lithium silicate glasses. Glass Physics And Chemistry , v. 12, p. 116-120, 1986.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Catalyzed crystal nucleation rate of mu and alfa-cordierite in the cordierite glass doped with TiO2. Glass Physics And Chemistry , v. 12, p. 480-483, 1986.

• Vedishcheva, N. M. ; Shakhmatkin, B. A. ; FOKIN, V. M. . Calorimetric study of crystalline rubidium borate and heats of glass crystallization. Glass Physics And Chemistry , v. 12, p. 484-487, 1986.

• Filipovich, V. N. ; Kalinina, A. M. ; FOKIN, V. M. ; Shishikina, E. K. ; Dmitriev, D. D. . Application of Kolmogorov's formula to the study of crystallization of glasses. Glass Physics and Chemistry , v. 9, p. 45-52, 1983.

• Kalinina, A. M. ; FOKIN, V. M. ; Shishikina, E. K. ; Filipovich, V. N. ; Dmitriev, D. D. . On application of Kolmogorov?s equation to glass crystallization study. Glass Physics And Chemistry , v. 9, p. 58-65, 1983.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. ; Shishikina, E. K. . Determination of mu-cordierite crystals nucleation rate in the non-stoichiometric glass of system MgO-Al2O3-SiO2-TiO2. Glass Physics And Chemistry , v. 8, p. 728-729, 1982.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Nucleation in silicate-glasses and effect of preliminary heat-treatment on it. Journal of Crystal Growth , v. 52, p. 115-121, 1981.

• Kalinina, A. M. ; Filipovich, V. N. ; FOKIN, V. M. . Stationary and nonstationary crystal nucleation rate in a glass of 2Na2O-CaO-3SiO2 stoichiometric composition. Journal of Non-Crystalline Solids , v. 38-39, p. 723-728, 1980.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. . Stationary and non-stationary 2Na2O-CaO-3SiO2 crystal nucleation rate in a glass of the same composition. Glass Physics And Chemistry , v. 6, p. 148-152, 1980.

• Mityushin, Y. B. ; FOKIN, V. M. ; Makhotenko, Y. A. . Automated scientific and technical-information system elektronic - research, development, implementation. NAUCHNO-TEKHNICHESKAYA INFORMATSIYA SERIYA 2 - INFORMATSIONNYE PROTSESSY I SISTEMY , v. 4, p. 5-13, 1978.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. . The crystal nucleation induction period in Li2O-2SiO2 glass and its temperature dependence. Glass Physics and Chemistry , v. 3, p. 113-119, 1977.

• FOKIN, V. M. ; Filipovich, V. N. ; Kalinina, A. M. . The effect of preliminary heat treatment on crystal nucleation in Li2O-2SiO2 glass. Glass Physics and Chemistry , v. 3, p. 119-125, 1977.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Time lag of Li2O-2SiO2 crystal nucleation and its temperature dependence. Glass Physics And Chemistry , v. 3, p. 122-129, 1977.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Investigation of preliminary heat treatment effect on crystal nucleation in Li2O-2SiO2 glass. Glass Physics And Chemistry , v. 3, p. 129-136, 1977.

• SEVASTYANOV, Y. S. ; FOKIN, V. M. ; Makhotenko, Y. A. . Conducting reviews of performance of information units at enterprises in an industry. NAUCHNO-TEKHNICHESKAYA INFORMATSIYA SERIYA 1 - ORGANIZATSIYA I METODIKA INFORMATSIONNOI RABOTY , v. 2, p. 10-13, 1976.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. . Method of determining the parameters characterizing crystal nucleation in glass. Glass Physics And Chemistry , v. 2, p. 298-305, 1976.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. . Determining the surface energy of the crystal-glass interface. Glass Physics And Chemistry , v. 1, p. 571-573, 1975.

• KREINGOL, F. I. ; FOKIN, V. M. . Exciton electroluminescence in Cu2O crystals. Soviet Physics Semiconductors , v. 4, p. 1888-1889, 1971.

• FOKIN, V.M. ; Cabral, A. A. ; Nascimento, M. L. F. ; ZANOTTO, E.D. ; SESTAK, J. . On the Application of DTA / DSC Methods for the Study of Glass Crystallization Kinetics. In: J. Sesták; M. Holecek; J. Malek. (Org.). Some Thermodynamic, Structural and Behavioral Aspects of Materials Accentuating Non-Crystalline States. 1ed.Praga: Academy of Sciences of Czech Republic, 2009, v. , p. 286-306.

• FOKIN, V. M. ; Yuritsyn, N. S. ; Zanotto, E. D. . Nucleation and Crystallization Kinetics in Silicate Glasses: Theory and Experiment. In: Jürn Williard P. Schmelzer. (Org.). Nucleation Theory and Applications. Berlin: Wiley-VCH, 2005, v. Unico, p. 74-125.

• Zanotto, E. D. ; FOKIN, V. M. . Surface energy calculation from crystal nucleation and growth kinetics in a TiO2-cordierite glass. In: Proceedings of XVIII Int. Congr. on Glass, 1998, San Francisco. Proceedings of XVIII Int. Congr. on Glass, 1998.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Crystal nucleation on glass surface. In: Proceedings XVII Int. Congr. on Glass, 1995, Beijing. Proceedings XVII Int. Congr. on Glass, 1995. v. 2. p. 218-223.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Filipovich, V. N. ; Kalinina, A. M. . Crystal nucleation on the surface of cordierite glass. In: Ceramic transactions, 1992. Ceramic transactions, 1992. v. 30. p. 372-382.

• Yuritsyn, N. S. ; FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Kinetic of crystal nucleation on the surface of cordierite glass. In: Proceedings XVI Int. Congr. on Glass, 1992, Madri. Proceedings XVI Int. Congr. on Glass, 1992. v. 5. p. 21-26.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. ; Müller, R. . On the determination of crystal nucleation rate by DTA method. In: Proceedings XV Int. Congr. on Glass, 1989, Leningrad. Proceedings XV Int. Congr. on Glass, 1989. v. 1a. p. 180-187.

• Filipovich, V. N. ; FOKIN, V. M. ; Kalinina, A. M. . Effect of frozen subcritical nuclei on crystal nucleation in glasses. In: Proceedings XV Int. Congr. on Glass, 1989, Leningrad. Proceedings XV Int. Congr. on Glass, 1989. v. 1a. p. 174-179.

• Kalinina, A. M. ; Filipovich, V. N. ; FOKIN, V. M. ; Sycheva, G. A. . Three types of catalysis of lithium disilicate crystal nucleation in lithium silicate glasses. In: Proceedings XIV Int. Congr. on Glass, 1986, New Dehli. Proceedings XIV Int. Congr. on Glass, 1986. v. 1. p. 366-373.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. ; Yuritsyn, N. S. . Crystal nucleation and growth at the surface of the glass of 2MgO-2Al2O3-5SiO2 composition. In: Proceeding VIII All-Union Conference ?Stekloobraznoe sostoyanie?, 1986, Leningrad. Proceeding VIII All-Union Conference ?Stekloobraznoe sostoyanie?, 1986. v. Unico. p. 235-236.

• Filipovich, V. N. ; FOKIN, V. M. ; Kalinina, A. M. . Problem of relation between structure of glass and its ability to volume crystallization. In: Proceeding VIII All-Union Conference ?Stekloobraznoe sostoyanie?, 1986, Leningrad. Proceeding VIII All-Union Conference ?Stekloobraznoe sostoyanie?, 1986. v. Unico. p. 124-131.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Catalyzed nucleation of mu and alfa-cordierite in the cordierite in titanic cordierite glass. In: Catalyzed crystallization of glasses, 1986, Moscow. Catalyzed crystallization of glasses, 1986. p. 90-93.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Stationary and non-stationary crystal nucleation in stoichiometric composition glass 2Na2O-CaO-3SiO2. In: Catalyzed Crystallization of Glasses, 1982, Moscow. Catalyzed Crystallization of Glasses, 1982. v. Unico. p. 46-53.

• Kalinina, A. M. ; FOKIN, V. M. ; Filipovich, V. N. . Non-stationary crystal nucleation rate in Li2O-2SiO2 glass and influence on it of preliminary heat treatment. In: Proceedings XI Int. Congr. on Glass, 1977, Prague. Proceedings XI Int. Congr. on Glass, 1977. v. 2. p. 11-20.

• FOKIN, V. M. ; Kalinina, A. M. ; Filipovich, V. N. . Crystal nucleation rate in soda-lime-silicate glass and its dependence on melting duration. In: Glass - Proceddings of Institute of Glass, 1975. Glass - Proceddings of Institute of Glass, 1975. v. Unico. p. 74-76.

• Kalinina, A. M. ; Filipovich, V. N. ; FOKIN, V. M. . Structure and properties of glass ceramic materials on the basis of rocks and slags. In: Proc. VII All-Union Conference, 1974, Chimkent. Proc. VII All-Union Conference, 1974. v. Unico. p. 27-33.

Projetos de pesquisa

• 2008 - Atual

  Formation of Pores in Stretched Highly Viscous Glass-forming Liquid, Descrição: Elastic stresses may play a remarkable role not only at cooling of partly crystallized glass-forming liquids but also, as was shown in [1, 2, 3], at crystallization processes. The elastic stresses in crystallization are due to the differences between the densities of glass and crystal. That is the reason why the effect of elastic stresses is of great important for glass-ceramic manufacture. In general, this effect depends on the density misfit, the geometry of the samples, and the kind of crystallization. Similarly to dissolved gases and especially to cavitation processes in liquids, elastic stresses could result in the formation of pores. It is known that a glass of diopside composition (CaO?MgO?2SiO2) reveal only surface crystallization [4]. This fact can by explained by strong difference in the densities of diopside crystal and respective liquid, which amounts about 15%. The full crystallization of powdered diopside glass results in the formation of pores. The crystal density estimated via the density of glass and the average volume fraction of pores agree with that estimated by X-ray studies [5]. It means that indeed the main reason of pore formation is misfit of densities. Therefore, we choose this glass to study the nucleation of pores under action of stretch stress. Moreover we show also that the growth rate of crystalline crust does not change up to full crystallization [6] but at some moment of time a pore appears that resolves the potential effect of elastic stress on crystal growth rate. Indeed, rough estimates demonstrate that evolving elastic stress energy could exceed the limit of glass strength earlier than its effect on growth rate becomes remarkable. [1] J. W. P. Schmelzer, R. Müller, J. Möller, I. Gutzow, J. Non-Cryst. Solids 315 (2003) 144. [2] V. M. Fokin, E. D. Zanotto, J. W. P. Schmelzer, O. V. Potapov, J. Non-Cryst. Solids 351 (2005) 149. [3] J. W. P. Schmelzer, E. D. Zanotto, I. Avramov, V. M. Fokin, J. Non-Cryst. Solids 352 (2006) 434.. , Situação: Em andamento; Natureza: Pesquisa. , Alunos envolvidos: Graduação: (1) / Mestrado profissional: (1) / Doutorado: (1) . , Integrantes: Vladimir Mikhailovich Fokin - Coordenador / Edgar Dutra Zanotto - Integrante / Marcio Luis Ferreira Nascimento - Integrante., Financiador(es): Fundação de Amparo à Pesquisa do Estado de São Paulo - Bolsa., Número de produções C, T & A: 13

• 2008 - Atual

  Re-examination of CNT in Connection with its Application to the Interpretation of Nucleation Experiment, Descrição: According to classical nucleation theory (CNT) based on Gibbs?s description of heterogeneous system both volume and surface thermodynamic properties of critical nuclei are considered as size independent. Therefore the thermodynamic driving force for the growth of macro crystals and its surface energy are usually attributed to the critical nuclei too [1, 2]. This assumption leads to the dramatic underestimation of steady-state nucleation rates if one considers surface energy as the temperature independent quantity [3]. The discrepancy between evaluated and experimental values of nucleation rate can be avoided if one assumes the slight growth of the specific interface energy with increasing temperature which may reflects the change of the critical size and hence the curvature of critical nucleus [4]. However this way leads to the values of surface energy very close to the experimental value for the proper liquid/vapor interface. This result conflicts with Stephan?s rule according to which the specific interfacial energy is proportionate to the enthalpy of the proper phase transformation [5]. In the case of the glass crystallization it is the melting and evaporation enthalpies. We plan to use for this aim our experimental data on crystal nucleation and growth kinetic in two silicate glasses with compositions of lithium disilicate (Li2O?2SiO2) and sodium calcium meta-silicate (Na2O?2CaO?3SiO2). Posed analysis will be performed in the capillarity approximation, i.e. following to CNT the surface energy will be considered as constant quantity Effective diffusion coefficient needed for analysis of nucleation process will be estimated from both crystal growth rates (measured at the temperatures of nucleation experiment) and time-lag for nucleation. [1] I. Gutzow, J. W. P. Schmelzer, The Vitreous State: Thermodynamics, Structure, Rheology and Crystallization, Springer, Berlin (1995). [2] P. F. James, Volume nucleation in silicate glasses: in Glasses and glass ceramics, pp.. , Situação: Em andamento; Natureza: Pesquisa. , Alunos envolvidos: Graduação: (2) / Mestrado profissional: (1) / Doutorado: (2) . , Integrantes: Vladimir Mikhailovich Fokin - Coordenador / Edgar Dutra Zanotto - Integrante / Marcio Luis Ferreira Nascimento - Integrante., Financiador(es): Fundação de Amparo à Pesquisa do Estado de São Paulo - Bolsa., Número de produções C, T & A: 29

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